The incident happened Tuesday evening in the 500 block of Toronto Avenue.
William Wales, 73, fatally struck, troopers said.
Administrative charge stems from actions during medical call last summer.
Two others were also injured in the two-vehicle crash Saturday on North Wynn Road.
Authorities pronounced Elizabeth Knapp, 62, dead at the scene.
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Ohio Attorney General’s Office announces agreement.
Jimell Woods, 25, injured Thursday night; Paris Jameson wounded Friday morning.
Police were called to scene on Dorr Street around 10:45 p.m.
James Friesel, 54, was taken into custody Thursday morning.